Dynamical Study of Competitive Model in Reaction Sr+HF→SrF+H

Key words: 
• LEPS potential energy surface /
• quasiclassical trajectory method /
• competitive mechanism /
• rotational alignment

Abstract: The quasiclassical trajectory method based on the extended LEPS potential energy surface has been employed here to investigate the reaction mechanism and features in the reaction Sr+HF→SrF+H at two reactional conditions (collision energy E c o l=54.18 kJ/mol, ν=0, j=0 and E c o l=7.56 kJ/mol, ν=1, j=0). The dynamical features in the competitive reaction modes are discussed and the stationary distribution function P ν(b) of the product SrF has already been deduced...